What controls the thickness of wetting layers near bulk criticality?

نویسندگان

  • Denis Fenistein
  • Daniel Bonn
  • Salima Rafaï
  • Gerard H Wegdam
  • Jacques Meunier
  • Andrew O Parry
  • Margarida M Telo da Gama
چکیده

We study the thickness of wetting layers in the binary-liquid mixture cyclohexane methanol. Far from the bulk critical point, the wetting layer thickness is independent of temperature, resulting from the competition between van der Waals and gravitational forces. Upon approaching the bulk critical temperature [t=(T(c)-T)/T(c)-->0], we observe that the wetting layer thickness diverges as t(-beta) with effective critical exponent beta=0.23+/-0.06. This is characteristic of a broad, intermediate scaling regime for the crossover from van der Waals wetting to critical scaling. We predict beta=beta/3 approximately 0.11, with beta the usual bulk-order parameter critical exponent, showing a small but significant difference with experiment.

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عنوان ژورنال:
  • Physical review letters

دوره 89 9  شماره 

صفحات  -

تاریخ انتشار 2002